This is a schematic of scanning photocurrent imaging microscopy of halide perovskite film (side view). Using the technique, researchers found the diffusion length within a well-oriented perovskite film measured up to 20 micrometers. Credit: Nano Letters
Solar cells made with films mimicking the structure of the mineral perovskite are the focus of worldwide research. But only now have researchers at Case Western Reserve University directly shown the films bear a key property allowing them to efficiently convert sunlight into electricity.
Identifying that attribute could lead to more efficient solar panels.
Electrons generated when light strikes the film are unrestricted by grain boundaries—the edges of crystalline subunits within the film—and travel long distances without deteriorating, the researchers showed. That means electric charge carriers that become trapped and decay in other materials are instead available to be drawn off as current.
The scientists directly measured the distance traveled—called diffusion length—for the first time by using the technique called "spatially scanned photocurrent imaging microscopy." Diffusion length within a well-oriented perovskite film measured up to 20 micrometers.
The findings, published in the journal Nano Letters, indicate that solar cells could be made thicker without harming their efficiency, said Xuan Gao, associate professor of physics and author of the paper.
"A thicker cell can absorb more light," he said, "potentially yielding a better solar cell."
Efficiency built in
Solar power researchers believe perovskite films hold great promise. In less than five years, films made with the crystalline structure have surpassed 20 percent efficiency in converting sunlight to electricity, a mark that took decades to reach with silicon-based solar cells used today.
In this research, Gao's lab performed spatially scanned photocurrent image measurements on films made in the lab of Case Western Reserve chemistry professor Clemens Burda.
Perovskite minerals found in nature are oxides of certain metals, but Burda's lab made organo-metallic films with the same crystalline structure using methyl ammonium lead tri-iodide (CH3NH3PBI3), a three-dimensional lead halide surrounded by small organic methyl ammonium molecules that hold the lattice structure together.
"The question has been, 'How are these solar cells so efficient? If we would know, we could further improve perovskite solar cells" Burda said. "People thought it could be due to unusually long electron transport, and we directly measured it."
Diffusion length is the distance an electron or its opposite, called a hole, travels from generation until it recombines or is extracted as electric current. The distance is the same as transport length when no electric field (which usually increases the distance traveled) is applied.
The labs made repeated measurements by focusing a tiny laser spot on films 8 millimeters square by 300 nanometers thick. The films were made stable by coating the perovskite with a layer of the polymer parylene.
The light generates electrons and holes and the photocurrent, or stream of electrons, is recorded between the electrodes positioned about 120 microns away from each other while the film is scanned along two perpendicular directions. The scanning yields a two-dimensional spatial map of carrier diffusion and transport characteristics.
The measurements showed diffusion length averaged about 10 microns. In some cases, the length reached 20 microns, showing the functional area of the film is at least 20 microns long, the researchers said.
In some materials, grain boundaries decrease conductivity, but imaging showed that these interfaces between grains in the film exerted no influence on electron travel. Gao and Burda say this may be because grains in the film are well aligned, causing no impedance or other detrimental effects on electrons or holes.
Burda and Gao are now seeking federal funds to use the microscopy technique to determine whether different grain sizes, orientations, halide perovskite compositions, film thicknesses and more change the film's properties, to further accelerate research in the field.
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More information: Shuhao Liu et al, Imaging the Long Transport Lengths of Photo-generated Carriers in Oriented Perovskite Films, Nano Letters (2016). DOI: 10.1021/acs.nanolett.6b04235